Transmittance

This article is about transmission through a volume. For transmission through a surface, see Fresnel equations.

File:Beer lambert1.png

Diagram of Beer-Lambert Law of transmittance of a beam of light as it travels through a cuvette of width l.

Earth's atmospheric transmittance over 1 nautical mile sea level path (infrared region). Because of the natural radiation of the hot atmosphere, the intensity of radiation is different from the transmitted part.

Transmittance of ruby in optical and near-IR spectra. Note the two broad blue and green absorption bands and one narrow absorption band on the wavelength of 694 nm, which is the wavelength of the ruby laser.

Transmittance of the surface of a material is its effectiveness in transmitting radiant energy. It is the fraction of incident electromagnetic power that is transmitted through a sample, in contrast to the transmission coefficient, which is the ratio of the transmitted to incident electric field.

Internal transmittance refers to energy loss by absorption, whereas (total) transmittance is that due to absorption, scattering, reflection, etc.

Mathematical definitions

Hemispherical transmittance

Hemispherical transmittance of a surface, denoted T, is defined as

$T = \frac{\Phi_\mathrm{e}^\mathrm{t}}{\Phi_\mathrm{e}^\mathrm{i}},$

where

• Φ_e^t is the radiant flux transmitted by that surface;
• Φ_eⁱ is the radiant flux received by that surface.

Spectral hemispherical transmittance

Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted T_ν and T_λ respectively, are defined as

$T_\nu = \frac{\Phi_{\mathrm{e},\nu}^\mathrm{t}}{\Phi_{\mathrm{e},\nu}^\mathrm{i}},$

$T_\lambda = \frac{\Phi_{\mathrm{e},\lambda}^\mathrm{t}}{\Phi_{\mathrm{e},\lambda}^\mathrm{i}},$

where

• Φ_e,ν^t is the spectral radiant flux in frequency transmitted by that surface;
• Φ_e,νⁱ is the spectral radiant flux in frequency received by that surface;
• Φ_e,λ^t is the spectral radiant flux in wavelength transmitted by that surface;
• Φ_e,λⁱ is the spectral radiant flux in wavelength received by that surface.

Directional transmittance

Directional transmittance of a surface, denoted T_Ω, is defined as

$T_\Omega = \frac{L_{\mathrm{e},\Omega}^\mathrm{t}}{L_{\mathrm{e},\Omega}^\mathrm{i}},$

where

• L_e,Ω^t is the radiance transmitted by that surface;
• L_e,Ωⁱ is the radiance received by that surface.

Spectral directional transmittance

Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted T_ν,Ω and T_λ,Ω respectively, are defined as

$T_{\nu,\Omega} = \frac{L_{\mathrm{e},\Omega,\nu}^\mathrm{t}}{L_{\mathrm{e},\Omega,\nu}^\mathrm{i}},$

$T_{\lambda,\Omega} = \frac{L_{\mathrm{e},\Omega,\lambda}^\mathrm{t}}{L_{\mathrm{e},\Omega,\lambda}^\mathrm{i}},$

where

• L_e,Ω,ν^t is the spectral radiance in frequency transmitted by that surface;
• L_e,Ω,νⁱ is the spectral radiance received by that surface;
• L_e,Ω,λ^t is the spectral radiance in wavelength transmitted by that surface;
• L_e,Ω,λⁱ is the spectral radiance in wavelength received by that surface.

Beer–Lambert law

Main article: Beer–Lambert law

By definition, transmittance is related to optical depth and to absorbance as

$T = e^{-\tau} = 10^{-A},$

where

• τ is the optical depth;
• A is the absorbance.

The Beer–Lambert law states that, for N attenuating species in the material sample,

$T = e^{-\sum_{i = 1}^N \sigma_i \int_0^\ell n_i(z)\mathrm{d}z} = 10^{-\sum_{i = 1}^N \varepsilon_i \int_0^\ell c_i(z)\mathrm{d}z},$

or equivalently that

$\tau = \sum_{i = 1}^N \tau_i = \sum_{i = 1}^N \sigma_i \int_0^\ell n_i(z)\,\mathrm{d}z,$

$A = \sum_{i = 1}^N A_i = \sum_{i = 1}^N \varepsilon_i \int_0^\ell c_i(z)\,\mathrm{d}z,$

where

• σ_i is the attenuation cross section of the attenuating specie i in the material sample;
• n_i is the number density of the attenuating specie i in the material sample;
• ε_i is the molar attenuation coefficient of the attenuating specie i in the material sample;
• c_i is the amount concentration of the attenuating specie i in the material sample;
• ℓ is the path length of the beam of light through the material sample.

Attenuation cross section and molar attenuation coefficient are related by

$\varepsilon_i = \frac{\mathrm{N_A}}{\ln{10}}\,\sigma_i,$

and number density and amount concentration by

$c_i = \frac{n_i}{\mathrm{N_A}},$

where N_A is the Avogadro constant.

In case of uniform attenuation, these relations become

$T = e^{-\sum_{i = 1}^N \sigma_i n_i\ell} = 10^{-\sum_{i = 1}^N \varepsilon_i c_i\ell},$

or equivalently

$\tau = \sum_{i = 1}^N \sigma_i n_i\ell,$

$A = \sum_{i = 1}^N \varepsilon_i c_i\ell.$

Cases of non-uniform attenuation occur in atmospheric science applications and radiation shielding theory for instance.

SI radiometry units

SI radiometry units

Quantity		Unit		Dimension	Notes
Name	Symbol	Name	Symbol	Symbol
Radiant energy	Qe	joule	J	M⋅L2⋅T−2	Energy of electromagnetic radiation.
Radiant energy density	we	joule per cubic metre	J/m3	M⋅L−1⋅T−2	Radiant energy per unit volume.
Radiant flux	Φe	watt	W or J/s	M⋅L2⋅T−3	Radiant energy emitted, reflected, transmitted or received, per unit time. This is sometimes also called "radiant power".
Spectral flux	Φe,ν or Φe,λ	watt per hertz or watt per metre	W/Hz or W/m	M⋅L2⋅T−2 or M⋅L⋅T−3	Radiant flux per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1.
Radiant intensity	Ie,Ω	watt per steradian	W/sr	M⋅L2⋅T−3	Radiant flux emitted, reflected, transmitted or received, per unit solid angle. This is a directional quantity.
Spectral intensity	Ie,Ω,ν or Ie,Ω,λ	watt per steradian per hertz or watt per steradian per metre	W⋅sr−1⋅Hz−1 or W⋅sr−1⋅m−1	M⋅L2⋅T−2 or M⋅L⋅T−3	Radiant intensity per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1. This is a directional quantity.
Radiance	Le,Ω	watt per steradian per square metre	W⋅sr−1⋅m−2	M⋅T−3	Radiant flux emitted, reflected, transmitted or received by a surface, per unit solid angle per unit projected area. This is a directional quantity. This is sometimes also confusingly called "intensity".
Spectral radiance	Le,Ω,ν or Le,Ω,λ	watt per steradian per square metre per hertz or watt per steradian per square metre, per metre	W⋅sr−1⋅m−2⋅Hz−1 or W⋅sr−1⋅m−3	M⋅T−2 or M⋅L−1⋅T−3	Radiance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅sr−1⋅m−2⋅nm−1. This is a directional quantity. This is sometimes also confusingly called "spectral intensity".
Irradiance	Ee	watt per square metre	W/m2	M⋅T−3	Radiant flux received by a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral irradiance	Ee,ν or Ee,λ	watt per square metre per hertz or watt per square metre, per metre	W⋅m−2⋅Hz−1 or W/m3	M⋅T−2 or M⋅L−1⋅T−3	Irradiance of a surface per unit frequency or wavelength. The terms spectral flux density or more confusingly "spectral intensity" are also used. Non-SI units of spectral irradiance include Jansky = 10−26 W⋅m−2⋅Hz−1 and solar flux unit (1SFU = 10−22 W⋅m−2⋅Hz−1).
Radiosity	Je	watt per square metre	W/m2	M⋅T−3	Radiant flux leaving (emitted, reflected and transmitted by) a surface per unit area. This is sometimes also confusingly called "intensity".
Spectral radiosity	Je,ν or Je,λ	watt per square metre per hertz or watt per square metre, per metre	W⋅m−2⋅Hz−1 or W/m3	M⋅T−2 or M⋅L−1⋅T−3	Radiosity of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. This is sometimes also confusingly called "spectral intensity".
Radiant exitance	Me	watt per square metre	W/m2	M⋅T−3	Radiant flux emitted by a surface per unit area. This is the emitted component of radiosity. "Radiant emittance" is an old term for this quantity. This is sometimes also confusingly called "intensity".
Spectral exitance	Me,ν or Me,λ	watt per square metre per hertz or watt per square metre, per metre	W⋅m−2⋅Hz−1 or W/m3	M⋅T−2 or M⋅L−1⋅T−3	Radiant exitance of a surface per unit frequency or wavelength. The latter is commonly measured in W⋅m−2⋅nm−1. "Spectral emittance" is an old term for this quantity. This is sometimes also confusingly called "spectral intensity".
Radiant exposure	He	joule per square metre	J/m2	M⋅T−2	Radiant energy received by a surface per unit area, or equivalently irradiance of a surface integrated over time of irradiation. This is sometimes also called "radiant fluence".
Spectral exposure	He,ν or He,λ	joule per square metre per hertz or joule per square metre, per metre	J⋅m−2⋅Hz−1 or J/m3	M⋅T−1 or M⋅L−1⋅T−2	Radiant exposure of a surface per unit frequency or wavelength. The latter is commonly measured in J⋅m−2⋅nm−1. This is sometimes also called "spectral fluence".
Hemispherical emissivity	ε			1	Radiant exitance of a surface, divided by that of a black body at the same temperature as that surface.
Spectral hemispherical emissivity	εν or ελ			1	Spectral exitance of a surface, divided by that of a black body at the same temperature as that surface.
Directional emissivity	εΩ			1	Radiance emitted by a surface, divided by that emitted by a black body at the same temperature as that surface.
Spectral directional emissivity	εΩ,ν or εΩ,λ			1	Spectral radiance emitted by a surface, divided by that of a black body at the same temperature as that surface.
Hemispherical absorptance	A			1	Radiant flux absorbed by a surface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptance	Aν or Aλ			1	Spectral flux absorbed by a surface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptance	AΩ			1	Radiance absorbed by a surface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptance	AΩ,ν or AΩ,λ			1	Spectral radiance absorbed by a surface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectance	R			1	Radiant flux reflected by a surface, divided by that received by that surface.
Spectral hemispherical reflectance	Rν or Rλ			1	Spectral flux reflected by a surface, divided by that received by that surface.
Directional reflectance	RΩ			1	Radiance reflected by a surface, divided by that received by that surface.
Spectral directional reflectance	RΩ,ν or RΩ,λ			1	Spectral radiance reflected by a surface, divided by that received by that surface.
Hemispherical transmittance	T			1	Radiant flux transmitted by a surface, divided by that received by that surface.
Spectral hemispherical transmittance	Tν or Tλ			1	Spectral flux transmitted by a surface, divided by that received by that surface.
Directional transmittance	TΩ			1	Radiance transmitted by a surface, divided by that received by that surface.
Spectral directional transmittance	TΩ,ν or TΩ,λ			1	Spectral radiance transmitted by a surface, divided by that received by that surface.
Hemispherical attenuation coefficient	μ	reciprocal metre	m−1	L−1	Radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral hemispherical attenuation coefficient	μν or μλ	reciprocal metre	m−1	L−1	Spectral radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Directional attenuation coefficient	μΩ	reciprocal metre	m−1	L−1	Radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral directional attenuation coefficient	μΩ,ν or μΩ,λ	reciprocal metre	m−1	L−1	Spectral radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
See also: SI · Radiometry · Photometry

See also

• Opacity (optics)