Ribulose-1,5-bisphosphate

Ribulose-1,5-bisphosphate

Skeletal formula of RuBP
Ball-and-stick model, based on x-ray diffraction data
Identifiers
CAS Number	14689-84-0
ChEBI	CHEBI:16710 Y
ChemSpider	110238 Y
Jmol 3D model	Interactive image
InChI InChI=1S/C5H12O11P2/c6-3(1-15-17(9,10)11)5(8)4(7)2-16-18(12,13)14/h3,5-6,8H,1-2H2,(H2,9,10,11)(H2,12,13,14)/t3-,5-/m1/s1 Y Key: YAHZABJORDUQGO-NQXXGFSBSA-N Y
SMILES O=P(O)(OCC(=O)[C@H](O)[C@H](O)COP(=O)(O)O)O
Properties
Chemical formula	C5H12O11P2
Molar mass	310.09 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Ribulose-1,5-bisphosphate (RuBP) is an organic substance that is involved in photosynthesis. It is a colourless anion. a double phosphate ester of the ketose (ketone-containing sugar) called ribulose. Salts of RuBP can be isolated, but its crucial biological function happens in solution. To simplify the presentation, the image in the above table depicts the acid form of this anion.

Role in photosynthesis

The Calvin cycle showing the role of ribulose-1,5-bisphosphate.

The enzyme ribulose bisphosphate carboxylase oxygenase (RuBisCO) catalyzes the reaction between RuBP and carbon dioxide. The product is the highly unstable 6-carbon intermediate known as 3-keto-2-carboxyarabinitol 1,5-bisphosphate. This six-carbon intermediate decays virtually instantaneously into two molecules of 3-phosphoglycerate (3-PGA) (see figure). RuBisCO also catalyzes RuBP with oxygen (O2) in a process called photorespiration, a process that is more prevalent at high temperatures. During photorespiration RuBP combines with O2 to become 3-PGA + phosphoglycolic acid. In the Calvin Cycle, RuBP is a product of the phosphorylation of ribulose-5-phosphate by ATP.