Hexachloroethane
| 200px | |
| 200px | |
| Names | |
|---|---|
| IUPAC name
Hexachloroethane
|
|
| Other names
Carbon hexachloride, Ethane hexachloride, Perchloroethane
|
|
| Identifiers | |
67-72-1  |
|
| ChEBI | CHEBI:39227 |
| ChEMBL | ChEMBL160929 |
| ChemSpider | 5979 |
| EC Number | 200-666-4 |
| Jmol 3D model | Interactive image |
| KEGG | C19248  |
| PubChem | 6214 |
| UNII | G30K3QQT4J |
|
|
|
|
| Properties | |
| C2Cl6 | |
| Molar mass | 236.74 g/mol |
| Appearance | colorless crystals[1] |
| Odor | camphor-like[1] |
| Density | 2.091 g/mL at 25 °C |
| Melting point | 183 to 185 °C (361 to 365 °F; 456 to 458 K) sublimes |
| 0.005% (22.2 °C)[1] | |
| Vapor pressure | 0.2 mmHg (20 °C)[1] |
| Vapor pressure | {{{value}}} |
|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
|
 verify (what is ?) |
|
| Infobox references | |
Hexachloroethane, also known as perchloroethane (PCA), C2Cl6, is a white crystalline solid at room temperature with a camphor-like odor.[2] It has been used by the military in smoke compositions, such as base-eject smoke munitions (smoke grenades).
Manufacture
Hexachloroethane is a byproduct of many industrial chlorination processes.[2] It is currently being manufactured directly in India.[3] The overall reaction is shown below. This reaction occurs stepwise.
- C2H6 + 6 Cl2 → C2Cl6 + 6 HCl
Applications
Hexachloroethane has been used in the formulation of extreme pressure lubricants. It has also been used as a chain transfer agent in the emulsion polymerization of propylene tetrafluoroethylene copolymer. Hexachloroethane has been used as an anthelmintic in veterinary medicine, a rubber accelerator, a component of fungicidal and insecticidal formulations as well as a moth repellant and a plasticizer for cellulose esters.[2]
Smoke grenades, called hexachloroethane (HCE) smoke or HC smoke, utilize a mixture containing roughly equal parts of HCE and zinc oxide and approximately 6% granular aluminium. These smokes are toxic, which is attributed to the production of zinc chloride (ZnCl2).[4]
Hexachloroethane has been used manufacture degassing pellets to remove hydrogen gas bubbles from molten aluminum in aluminum foundries. This use, as well as similar uses in magnesium, is being phased out in the European Union. It was phased out as early as 1999 in the United States.[3]
Toxicity
Hexachlorethane is not particularly toxic when taken orally,[5] but is considered to be quite toxic by skin adsorption. The primary effect is depression of the central nervous system.[2] The IDLH is given as 300 ppm and the OSHA PEL is 1 ppm (skin).[5] It is reasonably anticipated to be a carcinogen.[3]
References
- ↑ 1.0 1.1 1.2 1.3 Cite error: Invalid
<ref>tag; no text was provided for refs namedPGCH - ↑ 2.0 2.1 2.2 2.3 Lua error in package.lua at line 80: module 'strict' not found.
- ↑ 3.0 3.1 3.2 Lua error in package.lua at line 80: module 'strict' not found.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ 5.0 5.1 Lua error in package.lua at line 80: module 'strict' not found.
External links
- US Government Agency for Toxic Substances and Disease Registry ToxFAQs for Hexachloroethane
- US CDC NIOSH Pocket Guide to Chemical Hazards
- Scorecard.org chemical profile
- US EPA Hexachloroethane fact sheet
Lua error in package.lua at line 80: module 'strict' not found.
